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X-ray diffraction and thermal analysis of molybdenum(VI) oxide hemihydrate: monoclinic MoO3.1/2H2O

✍ Scribed by Fellows, R. L.; Lloyd, M. H.; Knight, J. F.; Yakel, H. L.


Book ID
126197233
Publisher
American Chemical Society
Year
1983
Tongue
English
Weight
411 KB
Volume
22
Category
Article
ISSN
0020-1669

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Structure of MoO3 Β· 1/2H2O by Convention
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The crystal structure of the compound \(\mathrm{MoO}_{3} \cdot 1 / 2 \mathrm{H}_{2} \mathrm{O}\) was solved ab initio from conventional X-ray powder diffraction data and refined by the Rietveld method. This hydrate crystallizes in the monoclinic space group \(P 2_{1} / m\) with unit cell dimensions

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New MoVI-dioxodialkyl complexes, MoOzR2(bipy), R = CH2CH2Ph and p-MeC6H4CH2; bipy = 2,2'-bipyridine, have been synthesized. The i.r. and the 1H-n.m.r. spectra of these complexes are noted. The structure of MoO2(o-MeC6H4CH2)z(bipy ) was determined by X-ray analysis. Significant differences in the red