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X-ray Diffraction, 7 Li MAS NMR Spectroscopy, and 119 Sn Mössbauer Spectroscopy Study of SnSb-Based Electrode Materials

✍ Scribed by Fernández-Madrigal, Francisco J.; Lavela, Pedro; Vicente, Carlos Pérez; Tirado, José L.; Jumas, Jean Claude; Olivier-Fourcade, Josette


Book ID
125959997
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
110 KB
Volume
14
Category
Article
ISSN
0897-4756

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Synchrotron X-ray single-crystal diffraction analyses revealed that as-synthesized and Na-exchanged RUB-29 (Cs 1Àx , Na x ) 14 Li 24 [Si 72 Li 18 O 172 ] . yH 2 O ðx ¼ 0; 0:9Þ displays the lattice symmetry I222. With increasing ion-exchange time, the Na cations preferentially replace Cs in the large