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X-ray crystal structure of the hydrochloride of 6-epicastanospermine [(1S,6R,7R,8R,8aR)-1,6,7,8-tetrahydroxy-octahydroindolizine]

✍ Scribed by Robert J. Nash; Linda E. Fellows; Aarti Girdhar; George W.J. Fleet; Josephine M. Peach; David J. Watkin; Mervyn P. Hegarty


Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
233 KB
Volume
29
Category
Article
ISSN
0031-9422

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(1R,2R,3S,5R,6R,7S,9aR,10aR)-4a,8a-DiΒ­az
✍ Furneaux, Richard H. ;Gainsford, Graeme J. ;Mason, Jennifer M. ;Tyler, Peter C. πŸ“‚ Article πŸ“… 2003 πŸ› International Union of Crystallography 🌐 English βš– 181 KB

The title compound, C 12 H 22 N 2 O 6 , is a linearly fused di(trihydroxypiperido)piperazine. The three six-membered rings adopt chair conformations with all the hydroxyl groups equatorial, and the ring fusion is the unusual transΒ±cisoidΒ±cis.