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X-ray crystal and molecular structure of [(η5C5H5)UCl3.2PPh3O]THF: trichloro(η5cyclopentadienyl) bis(triphenylphosphine oxide) uranium(IV).THF

✍ Scribed by G. Bombieri; G. de Paoli; A. Del Prà; K.W. Bagnall


Publisher
Elsevier Science
Year
1978
Weight
90 KB
Volume
14
Category
Article
ISSN
0020-1650

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The trichlorides of yttrium, samarium, and lutetium react with 2 equivalents of Na[C 5 H 4 t Bu] and 1 equivalent of NaBH 4 to give [(g 5 -C 5 H 4 t Bu) 2 LnBH 4 (THF)] (Ln = Y (1), Sm (2), Lu (3)) or with 2 equivalents of Na[C 5 Me 4 R] and 1 equivalent of NaBH 4 to form [(g 5 -C 5 Me 4 R) 2 ĹnBH 4