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## Abstract The ^13^C n.m.r. spectra of a series of 52 substituted norbornanes, norbornenes, bicyclo[2.2.2]octanes and ‐octenes have been recorded to examine the stereochemical effects of closely neighboring substituents on the carbon shieldings of these well‐defined molecular frameworks. These mod
A series of esters derived from synand anti-2-methyl-2-azabicyclo [ 2.2.2 ] octan-5-ols were synthesized and studied by 1H, 13C and 2D NMR spectroscopy. The crystal structure of 5-syn-(3,5-dichlorobenzoyloxy)-2-methyl-2azabicyclo [ 2.2.2 ] octane was determined by x-ray di †raction. The unambiguous
A series of esters derived from syn-and anti-2-methyl-2-azabicyclo[2.2.2]octan-6-ols were synthesized and studied by NMR spectroscopy. The unambiguous assignment of all bicyclic proton and carbon resonances was achieved by the combined analysis of the COSY, 1 H-13 C correlation spectra and double re