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X-ray Absorption Spectroscopy and Density Functional Theory Studies of [(H 3 buea)Fe III- X] n - (X = S 2- , O 2- , OH - ): Comparison of Bonding and Hydrogen Bonding in Oxo and Sulfido Complexes

โœ Scribed by Dey, Abhishek; Hocking, Rosalie K.; Larsen, Peter; Borovik, Andrew S.; Hodgson, Keith O.; Hedman, Britt; Solomon, Edward I.


Book ID
127227784
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
369 KB
Volume
128
Category
Article
ISSN
0002-7863

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โœ Ritu Bala; Raj Pal Sharma; Upendra Sharma; Andrew D. Burrows; Kevin Cassar ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 607 KB

The compounds [Co(NH 3 ) 6 ]Br 2 (BF 4 ) 1 and [Co(NH 3 ) 6 ]Cl 2 (HC 2 O 4 )AEH 2 O 2 have been prepared and structurally characterised. The two crystallographically independent cations in 1 are involved in different hydrogen bonding patterns, with one forming predominantly NAHร ร รF interactions w