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Wittig Reaction with Carbon Suboxide: Synthesis of Dimethyl 1,5-Diphenyl-1,2,3,4-pentatetraenedicarboxylate

✍ Scribed by Priv.-Doz. Dr. Franz W. Nader; Angelika Brecht


Publisher
John Wiley and Sons
Year
1986
Tongue
English
Weight
289 KB
Volume
25
Category
Article
ISSN
0044-8249

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Acyl chlorides are split into acyl and chlorine radicals by light of wavelength 254 my. Since the dissociation energy of the chlorine-hydrogen bond is considerably larger than that of the acyl-hydrogen bond, substitution of the substrate by acyl radicals is observed on irradiation of acid chlorides.