Why is understanding glassy polymer mechanics so difficult?

✍ Scribed by Robert S. Hoy

• Publisher: John Wiley and Sons
• Year: 2011
• Tongue: English
• Weight: 248 KB
• Volume: 49
• Category: Article
• ISSN: 0887-6266
• DOI: 10.1002/polb.22276

✦ Synopsis

Abstract

In this Perspective, I describe recent work on systems in which the traditional distinctions between (i) unentangled versus well‐entangled systems and (ii) melts versus glasses seem least useful, and argue for the broader use in glassy polymer mechanics of two more dichotomies: systems which possess (iii) unary versus binary and (iv) cooperative versus noncooperative relaxation dynamics. I discuss the applicability of (iii–iv) to understanding the functional form of strain hardening. Results from molecular dynamics simulations show that the “dramatic” hardening observed in densely entangled systems is associated with a crossover from unary, noncooperative to binary, cooperative relaxation as strain increases; chains stretch between entanglement points, altering the character of local plasticity. Promising approaches for future research along these lines are discussed. © 2011 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys, 2011