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Why Does Water Accelerate Organic Reactions under Heterogeneous Condition?

✍ Scribed by Manna, Arpan; Kumar, Anil


Book ID
121368596
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
715 KB
Volume
117
Category
Article
ISSN
1089-5639

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Water-promoted organic reactions. aldol
✍ AndreΒ΄ Lubineau; Elsa Meyer πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 359 KB

As a consequence of the hydrophobic effect, the reaction between silyl enol ethers and aldehydes are shown to proceed without a catalyst in aqueous solution and neutral conditions providing crossed-aldol products with a 2Y~ selectivity, as under pressure, that is the reverse in comparison with the a