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Wheel-Shaped ErIIIZnII3 Single-Molecule Magnet: A Macrocyclic Approach to Designing Magnetic Anisotropy

✍ Scribed by Aika Yamashita; Akiko Watanabe; Prof. Dr. Shigehisa Akine; Prof. Dr. Tatsuya Nabeshima; Prof. Dr. Motohiro Nakano; Dr. Tomoo Yamamura; Prof. Dr. Takashi Kajiwara

Book ID
102723734
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
544 KB
Volume
123
Category
Article
ISSN
0044-8249

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A Wheel-Shaped Single-Molecule Magnet of
A Wheel-Shaped Single-Molecule Magnet of [MnII3MnIII4]: Quantum Tunneling of Magnetization under Static and Pulse Magnetic Fields
✍ Satoshi Koizumi; Masayuki Nihei; Takuya Shiga; Motohiro Nakano; Hiroyuki Nojiri; 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 541 KB

## Abstract The reaction of __N__‐(2‐hydroxy‐5‐nitrobenzyl)iminodiethanol (=H~3~(5‐NO~2~‐hbide)) with Mn(OAc)~2~⋅ 4 H~2~O in methanol, followed by recrystallization from 1,2‐dichloroethane, yielded a wheel‐shaped single‐molecule magnet (SMM) of [Mn^II^~3~Mn^III^~4~(5‐NO~2~‐hbide)~6~]⋅5 C~2~H~4~Cl~2