Photoreactivity of the (2,2′-bipyridyl)h
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B. Sieklucka; J. Szklarzewicz; A. Samotus
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Article
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1993
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Elsevier Science
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English
⚖ 263 KB
The electronic spectrum of the \(\mathrm{W}(\mathrm{bpy})(\mathrm{CN})_{5}{ }^{2-}\) ion (bpy, \(2,2^{\prime}\)-bipyridyl) in the visible region is dominated by metal-to-ligand charge transfer (MLCT) transitions. The complex undergoes photosubstitution with the preferential loss of the bpy ligand. T