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Well-defined poly(2-hydroxyethyl methacrylate) and its amphiphilic block copolymers via acidolysis of anionically synthesized poly(2-vinyloxyethyl methacrylate)

✍ Scribed by Eli Ruckenstein; Hongmin Zhang


Book ID
106002769
Publisher
Springer
Year
2001
Tongue
English
Weight
142 KB
Volume
47
Category
Article
ISSN
0170-0839

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The vinyl of the ester group of 2-vinyloxyethyl methacrylate was first selectively reacted with acetic acid to obtain 2-[1-(acetoxy)ethoxy]ethyl methacrylate ( 2). This protected monomer was subjected to anionic polymerization in tetrahydrofuran at 060ЊC in the presence of LiCl, using 1,1-diphenylhe

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## Abstract Anionic polymerizations of 2‐[(trimethylsilyl)oxy]ethyl methacrylate (1), 2‐[(__tert__‐butyldimethylsilyl)oxy]ethyl methacrylate (2), and 2‐[(methoxymethyl)oxy]ethyl methacrylate (3), the protected forms of 2‐hydroxyethyl methacrylate (HEMA), were carried out in THF at βˆ’78Β°C with 1,1‐di