The vinyl of the ester group of 2-vinyloxyethyl methacrylate was first selectively reacted with acetic acid to obtain 2-[1-(acetoxy)ethoxy]ethyl methacrylate ( 2). This protected monomer was subjected to anionic polymerization in tetrahydrofuran at 060ΠC in the presence of LiCl, using 1,1-diphenylhe
β¦ LIBER β¦
Well-defined poly(2-hydroxyethyl methacrylate) and its amphiphilic block copolymers via acidolysis of anionically synthesized poly(2-vinyloxyethyl methacrylate)
β Scribed by Eli Ruckenstein; Hongmin Zhang
- Book ID
- 106002769
- Publisher
- Springer
- Year
- 2001
- Tongue
- English
- Weight
- 142 KB
- Volume
- 47
- Category
- Article
- ISSN
- 0170-0839
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## Abstract Anionic polymerizations of 2β[(trimethylsilyl)oxy]ethyl methacrylate (1), 2β[(__tert__βbutyldimethylsilyl)oxy]ethyl methacrylate (2), and 2β[(methoxymethyl)oxy]ethyl methacrylate (3), the protected forms of 2βhydroxyethyl methacrylate (HEMA), were carried out in THF at β78Β°C with 1,1βdi