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Weitere Reaktionen des Amino(imino)borans Me3Si(tBu)N*B*NtBu und des Alkyliden(amino)borans Me3Si(tBu)N=B=CHtBu

✍ Scribed by Braunschweig, Holge ;Paetzold, Peter ;Spaniol, Thomas P.

Publisher
Wiley (John Wiley & Sons)
Year
1993
Tongue
English
Weight
459 KB
Volume
126
Category
Article
ISSN
0009-2940

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✍ E. Bulak; T. Varnal; P. Paetzold; U. Englert 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 German ⚖ 78 KB 👁 1 views

The formation of four products of the type Me ) and the hydroboranes (R' 2 BH) 2 is described. Crystal structure analysis re-veals the molecule 1 to have an N=B±N=B backbone with two orthogonal N=B bond planes and, hence, no conjugation between the two B±N double bonds.