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Weakly-coordinating anions stabilise the unprecedented monovalent and divalent η-benzene nickel cations [(η-C5H5)Ni(η-C6H6)Ni(η-C5H5)]2+ and [Ni(η-C6H6)2]2+

✍ Scribed by Priego, José L.; Doerrer, Linda H.; Rees, Leigh H.; Green, Malcolm. L. H.


Book ID
121402589
Publisher
Royal Society of Chemistry
Year
2000
Tongue
English
Weight
468 KB
Volume
9
Category
Article
ISSN
1359-7345

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1,6-Heptadien-Nickel(0)-Komplexe:rac/mes
✍ Proft, Bernd ;Pörschke, Klaus-Richard ;Lutz, Frank ;Krüger, Carl 📂 Article 📅 1991 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 909 KB

Alkene ligands / 1,6-Dienes / Nickel complexes 1.6-Heptadiene Nickel(0) Complexes: rac/meso-(p-q2,11'-C,H Ni(CDT) dissolves in 1,6-heptadiene with displacement of the CDT to yield the dinuclear homoleptic product rac/meso-(p-r12,~2-C;rH12)~Ni(~2,rlZ-C;rH12))2 (1) as a mixture of stereoisomers, in wh