Weakly allowed transitions in the spin-lattice relaxation of spin pairs
β Scribed by A.M. Stoneham
- Publisher
- Elsevier Science
- Year
- 1966
- Weight
- 171 KB
- Volume
- 21
- Category
- Article
- ISSN
- 0031-9163
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π SIMILAR VOLUMES
A series of the d 6 iron(I1) complexes with bulky organic ligands (like [ Fe(bzpy),(NCS),]) can exist in two spin forms: in the low-spin ( S = 0) form at low temperature and in the high-spin ( S = 2) form at high temperature. In the crystal phase, the transition between these two forms may be either
The Redfield formalism is used to describe nuclear spin relaxation in weakly coupled spin-pair systems for which differential relaxation is both expected and observed. The utility of longitudinal versus transverse relaxation studies is explored with respect to fully characterizing the molecular para