Long-pathlength Fourier transform spectra of water vapor recorded previously by Schermaul et al. (J. Mole. Spectrosc. 211, 169 (2002)) are analyzed in the range 11 787-13 554 cm -1 . Wavenumbers, absolute intensities, and self-broadening coefficients, with associated uncertainties, are presented for
Weak Line Water Vapor Spectra in the Region 13 200–15 000 cm−1
✍ Scribed by Roland Schermaul; Richard C.M. Learner; A.A.D. Canas; J.W. Brault; Oleg L. Polyansky; Djedjiga Belmiloud; Nikolai F. Zobov; Jonathan Tennyson
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 370 KB
- Volume
- 211
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
✦ Synopsis
New Fourier transform spectra of water vapor are presented in the range 6500-16 400 cm -1 obtained using pathlengths of up to 800 m and long integration times. These spectra have a significantly higher signal-to-noise than previous measurements in this wavenumber range. Wavenumbers, absolute intensities and self-broadening coefficients, all with associated uncertainties, are presented for 3604 lines in the region 13 200-15 000 cm -1 . Analysis of these lines using variational linelists, along with other unassigned lines from previous studies, has been conducted. This leads to 952 new line assignments to transitions involving 35 different vibrational states of H 2 16 O. A smaller number of lines are assigned to H 2 18 O and H 2 17 O.
📜 SIMILAR VOLUMES
New laboratory measurements are presented for the near-infrared and visible spectrum (8600-15 000 cm -1 ) of water vapor. Spectral line parameters, principally intensities and air-broadening coefficients, are derived from Fourier transform spectroscopic measurements at high resolution (0.03 cm -1 ),
The new laboratory measurements of R. Schermaul et al. (J. Mol. Spectrosc. 208), for the near-infrared and visible spectrum of water vapor, covering the 2ν + δ, 3ν, 3ν + δ, and 4ν polyads, are combined with accurate calculations of weaker lines to provide a new, comprehensive linelist of water trans
The pure rotational and rovibrational spectra of H 13 C 15 NO, an isotopically substituted species of the quasilinear molecule fulminic acid, were investigated by means of microwave, millimeter-wave, and Fourier-transform infrared spectroscopy. The pure rotational spectra were measured in the spectr