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Weak interactions and the tunneling racemization

✍ Scribed by M. Cattani; J. M. F. Bassalo

Publisher: John Wiley and Sons
Year: 1998
Tongue: English
Weight: 66 KB
Volume: 10
Category: Article
ISSN: 0899-0042
DOI: 10.1002/(sici)1520-636x(1998)10:6<519::aid-chir3>3.0.co;2-z

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✦ Synopsis

Assuming the active molecule as a two-level system, we calculate the racemization, due to the tunneling effect, taking into account the effects of the weak interactions and of an external potential. We show that the weak interactions would block the tunneling racemization of enantiomers in compressed gases and liquids.

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