Water Vapor Measurements between 590 and 2582 cm−1: Line Positions and Strengths
✍ Scribed by Robert A. Toth
- Book ID
- 102972240
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 750 KB
- Volume
- 190
- Category
- Article
- ISSN
- 0022-2852
No coin nor oath required. For personal study only.
✦ Synopsis
This study involves measurements of H216O, H217O, and H218O vapor spectra for the region between 590 and 2582 cm-1. The parameters derived from the data include line positions, energy levels, and linestrengths. The study involves high-resolution line-position measurements with samples at room temperature in the (000)-(000), (010)-(010), and (010)-(000) bands. The experimental frequencies were used along with microwave, far-infrared, and hot water emission measurements in an analysis to obtain high-accuracy rotational energy level values in the (000), and (010) vibrational states of H216O for J </= 20. The experimental linestrengths were fitted by least squares to a model in which the dipole moment was represented as a series expansion containing up to 19 dipole moment matrix elements. The measurements in this work were more extensive than reported in prior studies by this author for the (010)-(000) band. Copyright 1998 Academic Press.
📜 SIMILAR VOLUMES
The water vapor linestrengths in the region of the 3n / d resonance polyad of interacting vibrational states ( the corresponding upper states are ( 310 ) , ( 211) , ( 112) , ( 013) , ( 131) , ( 230) , ( 032 ) , and ( 051) ) have been analyzed leading to accurate dipole moment transition parameters.