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Water Vapor Measurements between 590 and 2582 cm−1: Line Positions and Strengths

✍ Scribed by Robert A. Toth


Book ID
102972240
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
750 KB
Volume
190
Category
Article
ISSN
0022-2852

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✦ Synopsis


This study involves measurements of H216O, H217O, and H218O vapor spectra for the region between 590 and 2582 cm-1. The parameters derived from the data include line positions, energy levels, and linestrengths. The study involves high-resolution line-position measurements with samples at room temperature in the (000)-(000), (010)-(010), and (010)-(000) bands. The experimental frequencies were used along with microwave, far-infrared, and hot water emission measurements in an analysis to obtain high-accuracy rotational energy level values in the (000), and (010) vibrational states of H216O for J </= 20. The experimental linestrengths were fitted by least squares to a model in which the dipole moment was represented as a series expansion containing up to 19 dipole moment matrix elements. The measurements in this work were more extensive than reported in prior studies by this author for the (010)-(000) band. Copyright 1998 Academic Press.


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The Water Vapor Linestrengths between 11
✍ J.-M. Flaud; C. Camy-Peyret; A. Bykov; O. Naumenko; T. Petrova; A. Scherbakov; L 📂 Article 📅 1997 🏛 Elsevier Science 🌐 English ⚖ 867 KB

The water vapor linestrengths in the region of the 3n / d resonance polyad of interacting vibrational states ( the corresponding upper states are ( 310 ) , ( 211) , ( 112) , ( 013) , ( 131) , ( 230) , ( 032 ) , and ( 051) ) have been analyzed leading to accurate dipole moment transition parameters.