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Water-tolerant enantioselective carbonyl-ene reactions with palladium(II) and platinum(II) Lewis acid catalysts bearing BINAP

โœ Scribed by He-Kuan Luo; Hai-Yan Yang; Tan Xiang Jie; Ong Siong Chiew; Herbert Schumann; Lim Bee Khim; Christina Lim


Book ID
104057127
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
466 KB
Volume
261
Category
Article
ISSN
1381-1169

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Enantioselective Carbonyl-Ene Reactions
โœ He-Kuan Luo; Lim Bee Khim; Herbert Schumann; Christina Lim; Tan Xiang Jie; Hai-Y ๐Ÿ“‚ Article ๐Ÿ“… 2007 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 245 KB

## Abstract The palladium(II)โ€BINAPโ€catalyzed enantioselective carbonylโ€ene reactions between ten arylglyoxals and five alkenes were systematically investigated and demonstrated good to excellent enantioselectivities with high __ee__ values of up to 93.8โ€‰%. The results showed that both arylglyoxals