Photosystem II complexes of higher plants are structurally and functionally heterogeneous. While the only clearly defined structural difference is that Photosystem II reaction centers are served by two distinct antenna sizes, several types of functional heterogeneity have been demonstrated. Among th
✦ LIBER ✦
Water-splitting manganese complex controls light-induced redox changes of cytochromeb559in Photosystem II
✍ Scribed by Rakesh Kumar Sinha; Arjun Tiwari; Pavel Pospíšil
- Publisher
- Springer US
- Year
- 2010
- Tongue
- English
- Weight
- 221 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0145-479X
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## Abstract A dinuclear manganese complex {[Mn~2~^II,III^L(μ‐OAc)~2~]ClO~4~} has been synthesised, where L is the dianion of 2‐{[bis(pyrid‐2‐ylmethyl)amino]methyl}‐6‐{[(3,5‐di‐__tert__‐butyl‐2‐hydroxybenzyl)(pyrid‐2‐ylmethyl)amino]methyl}‐4‐methylphenol, an unsymmetric binucleating ligand with two