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Water-Soluble Polymeric Thioxanthone Photoinitiator Containing Glucamine as Coinitiator

✍ Scribed by Xuesong Jiang; Jie Yin

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
306 KB
Volume
209
Category
Article
ISSN
1022-1352

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✦ Synopsis

Abstract

A novel kind of water‐soluble polymeric photoinitiator was synthesized by introducing thioxanthone moieties and glucamine into the polymeric chain, as well as low‐molecular weight model compounds. The photochemical and photophysical properties of these photoinitiators were studied. PTX‐GA possesses a similar UV‐vis absorption, weaker fluorescence emission and a shorter lifetime of the TX triplet state (τ) as compared to TX‐MGA and TX‐PMAC/MDEA. ESR showed that in TX‐PMAC/MDEA the smallest number of radicals is generated. Photopolymerization of arylamide and methylene bisacryamide initiated by these photoinitiators shows that PTX‐GA is more effective than TX‐MGA and TX‐PMAC/MDEA.

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📜 SIMILAR VOLUMES

Polymeric Photoinitiator Containing In-C
Polymeric Photoinitiator Containing In-Chain Thioxanthone and Coinitiator Amines
✍ Xuesong Jiang; Jie Yin 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 103 KB

## Abstract **Summary:** A polymeric photoinitiator (PTXP) containing in‐chain thioxanthone (TX) and coinitiator amines was synthesized by step‐growth polymerization, as well as low‐molecular‐weight model compounds. Photopolymerizations of methyl methacrylate (MMA) initiated by these photoinitiator