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Water-Soluble Organometallic Compounds. 6. 1 Synthesis, Spectral Properties, and Crystal Structures of Complexes of 1,3,5-Triaza-7-phosphaadamantane with Group 10 Metals

✍ Scribed by Darensbourg, Donald J.; Decuir, Tara J.; Stafford, Nicole White; Robertson, Jeffrey B.; Draper, Jennifer D.; Reibenspies, Joseph H.; Kathó, Agnes; Joó, Ferenc

Book ID: 120601560
Publisher: American Chemical Society
Year: 1997
Tongue: English
Weight: 258 KB
Volume: 36
Category: Article
ISSN: 0020-1669
DOI: 10.1021/ic970238x

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Synthesis, Reactivity, X-ray Crystal Str

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## Abstract A series of chloridoruthenium(II) complexes bearing the tripodal ligand tris(pyrazolyl)borate (Tp), the water‐soluble cage phosphane 1,3,5‐triaza‐7‐phosphaadamantane (PTA) and its __N__‐boranyl adduct PTA(BH~3~), together with PPh~3~, have been synthesised. The corresponding monohydrido