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Water-soluble metal complexes and catalysts. Part 7. New efficient water-soluble catalysts for two-phase olefin hydroformylation: BINAS-Na, a superlative in propene hydroformylation

โœ Scribed by Wolfgang A. Herrmann; Christian W. Kohlpaintner; Rainer B. Manetsberger; Helmut Bahrmann; Hariolf Kottmann


Book ID
108046601
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
743 KB
Volume
97
Category
Article
ISSN
1381-1169

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Water-soluble metal complexes and cataly
โœ Denys Baskakov; Wolfgang A. Herrmann ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 278 KB

Novel water-soluble ligands were prepared in high yields by condensation of various amino acids with tris(hydroxymethyl)phosphane. Rhodium complexes of these ligands, formed in situ, were tested in two-phase hydroformylation of propylene. Selectivity observed with these ligand systems is easily cont