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Water-Soluble Carbon Nanotubes by Redox Radical Polymerization

✍ Scribed by Dimitrios Tasis; Kostas Papagelis; Maurizio Prato; Ioannis Kallitsis; Constantinos Galiotis


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
258 KB
Volume
28
Category
Article
ISSN
1022-1336

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✦ Synopsis


Abstract

Water‐soluble single‐ and multi‐walled carbon nanotubes (CNTs) were prepared by grafting polyacrylamide chains from the graphitic surface via ceric ion‐induced redox radical polymerization. The reducing functionalities were covalently attached to the tubes by peroxide‐assisted radical reaction. The results showed that polymer chains were grafted onto CNTs by the redox process. The redox radical polymerization initiated by carbon nanotube‐bearing functionalities not only provides a powerful strategy for modifying the carbon nanostructures but also gives us the knowledge of their sidewall chemistry.

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