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Water on silica and silicate surfaces. III. Hexamethyldisilazane-treated silica surfaces

โœ Scribed by A.C Zettlemoyer; H.H Hsing


Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
474 KB
Volume
55
Category
Article
ISSN
0021-9797

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๐Ÿ“œ SIMILAR VOLUMES


Mechanism and Kinetics of Hexamethyldisi
โœ V.M. Gun'ko; M.S. Vedamuthu; G.L. Henderson; J.P. Blitz ๐Ÿ“‚ Article ๐Ÿ“… 2000 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 243 KB

Quantum chemical calculations of the reaction of hexamethyldisilazane with silica indicates a two-step mechanism. The first, rate-determining step results in trimethylsilylation of a surface silanol and formation of trimethylaminosilane. The second step involves reaction of a trimethylaminosilane re