Water as an efficient medium for the synthesis of cyclic carbonate
β Scribed by Jian Sun; Junyi Ren; Suojiang Zhang; Weiguo Cheng
- Book ID
- 104096023
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- French
- Weight
- 174 KB
- Volume
- 50
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Herein we report an efficient method for synthesis of b-alkylated and b,b-dialkylated a-iodo enol ethers in water. Radical addition in aqueous medium of ethyl iodoacetate, iodoacetonitrile, and iodoacetamide to ynol ethers leads to a-iodo enol ethers with moderate to excellent yields and high stereo
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
Decarbonylation of the tertiary aldehydes 4-ethyl-4-formyl-hexanenitrile (2) and 2-methyl-2-phenylpropanal (4) promoted by dioxygen occurs at room temperature only if suspended in water probably via the sequential acyl radical-CO liberation-tertiary radical that is promoted by an 'on water' process