Water-Accelerated Organometallic Chemist
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Peter Wipf; Ruth L. Nunes; Seth Ribe
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Article
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2002
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John Wiley and Sons
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German
⚖ 135 KB
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Dedicated to Professor Dieter Seebach on the occasion of his 65th birthday Carboalumination of alkynes in the presence of catalytic Cp 2 ZrCl 2 and H 2 O affords vinyl-alane intermediates, which serve as nucleophiles in the subsequent addition to enantiomerically enriched (tertbutyl)-and (para-tolyl