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Watching hydrogen-bond dynamics in a β-turn by transient two-dimensional infrared spectroscopy

✍ Scribed by Kolano, Christoph; Helbing, Jan; Kozinski, Mariusz; Sander, Wolfram; Hamm, Peter


Book ID
109896336
Publisher
Nature Publishing Group
Year
2006
Tongue
English
Weight
602 KB
Volume
444
Category
Article
ISSN
0028-0836

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The cis/trans conformational equilibrium of the two Ac-Pro isomers of the beta-turn model dipeptide [13C]-Ac-L-Pro-D-Ala-NHMe, 98% 13C enriched at the acetyl carbonyl atom, was investigated by the use of variable temperature gradient enhanced 1H-nmr, two-dimensional (2D) 1H,1H nuclear Overhauser eff