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W18O49 nanorods decorated with Ag/AgCl nanoparticles as highly-sensitive gas-sensing material and visible-light-driven photocatalyst

✍ Scribed by Shibin Sun; Xueting Chang; Lihua Dong; Yidong Zhang; Zhenjiang Li; Yanyan Qiu


Book ID
104030887
Publisher
Elsevier Science
Year
2011
Tongue
English
Weight
813 KB
Volume
184
Category
Article
ISSN
0022-4596

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✦ Synopsis


A novel gas-sensing material and photocatalyst was successfully obtained by decorating Ag/AgCl nanoparticles on the W 18 O 49 nanorods through a clean photochemical route. The as-prepared samples were characterized using combined techniques of X-ray diffractometry, electron microscopy, energy dispersive X-ray spectrometry, and X-ray photoelectron spectroscopy. Gas-sensing measurements indicate that the Ag/AgCl/W 18 O 49 NRs sensors exhibit superior reducing gas-sensing properties to those of bare W 18 O 49 NRs, and they are highly selective and sensitive to NH 3 , acetone, and H 2 S with short response and recovery times. The Ag/AgCl/W 18 O 49 NRs photocatlysts also possess higher photocatalytic performance than bare W 18 O 49 NRs for degradation of methyl orange under simulated sunlight irradiation. Possible mechanisms concerning the enhancement of gas-sensing and photocatalytic activities of the Ag/AgCl/W 18 O 49 NRs composite were proposed.