VUV fluorescence from the UV-multiphoton dissociation of chlorinated methanes

✍ Scribed by H.K. Haak; F. Stuhl

• Publisher: Elsevier Science
• Year: 1979
• Tongue: English
• Weight: 389 KB
• Volume: 68
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(79)87225-5

✦ Synopsis

Se=& chlorinated methanes (CC4, CHCI3, CH+&.. CH3CI. CH4) and Cl2 were photolyzed with 193 nm ArF Iaser light_ Upon irradiation OfCCb, CHCI3, and CH2CI2 vacuum W emission is observed which is attributed to wdhtion from excited Cig_ The escited moIecules are probably formed by sequential absorption of two photons via a dissociative state of the parent moIecuIe.