## Abstract An IR laser absorption diagnostic has been further developed for accurate and sensitive timeβresolved measurements of ethylene in shock tube kinetic experiments. The diagnostic utilizes the P14 line of a tunable CO~2~ gas laser at 10.532 ΞΌm (the (0 0 1) β (1 0 0) vibrational band) and a
V.U.V. absorption diagnostic for shock tube kinetics studies of C2H4
β Scribed by Larry S. Zelson; David F. Davidson; Ronald K. Hanson
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 985 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0022-4073
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π SIMILAR VOLUMES
Concentration-time profiles have been measured for hydroxyl radicals generated by the shock-tube decomposition of hydrogen peroxide in the presence of a variety of additives. At temperatures close to 1300"K, the rate constants for the reaction OH + R H + R + HzO arr found to be in the ratio 0.18:0.
The ab initio electronic structure calculations at the MP2 and the Becke Ε½ . 3LYP density functional levels in conjunction with the 6-311qqG 2 df, 2 pd basis set were used for the determination of the structure, vibrational spectra, and dissociation 2q 2q Ε½ . energies of the XH and XH X s C, Si, Ge