𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Vortex inhibition: A new viscoelastic effect with importance in drag reduction and polymer characterization

✍ Scribed by R. J. Gordon; C. Balakrishnan


Publisher
John Wiley and Sons
Year
1972
Tongue
English
Weight
493 KB
Volume
16
Category
Article
ISSN
0021-8995

No coin nor oath required. For personal study only.

✦ Synopsis


We recently reported a new viscoelastic effect, wherein remarkably small quantities of certain high molecular weight polymers inhibit the tendency of water to form a vortex, as it drains from a large tank. This phenomenon is referred to as vortex inhibition (V.I.). Here, we examine the influence of molecular weight and molecular weight distribution on V.I. and the close relationship between those polymers which reduce drag and those which exhibit vortex inhibition. It has also been found that V.I. is a sensitive measure of polymer degradation, much more so than intrinsic viscosity. The significance of these findings in drag reduction, and for macromolecular characterization in general, is discussed.