Vomifoliol 9-O-β-d-glucopyranosyl-4-O-β-d-xylopyranosyl-6-O-β-d-glucopyranoside: A trisaccharide glycoside from apple fruit
✍ Scribed by Markus Herderich; Werner Feser; Peter Schreier
- Book ID
- 103339094
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 346 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0031-9422
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Condensation of allyl 3,4-di-O-benzyl-beta-D-xylopyranoside with 2-O-acetyl-3,4,6-tri-O-benzyl-alpha-D-galactopyranosyl chloride in dichloromethane in the presence of silver triflate gave allyl 2-O-(2-O-acetyl-3,4-6-tri-O-benzyl-beta-D-galactopyranosyl)-3,4-di-O benzyl-beta-D-xylopyranoside (7, 83%)
The molecule of the title compound, C 29 H 35 ClO 15 S, possesses normal geometric parameters. Intermolecular C-HÁ Á ÁO hydrogen-bond interactions are responsible for the supramolecular assembly of the complex molecules into a threedimensional framework.