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Volumetric study on a Co(III) rotaxane complex in aqueous solutions at 25°C

✍ Scribed by K. Takaizumi; T. Wakabayashi; H. Ogino


Publisher
Springer US
Year
1996
Tongue
English
Weight
292 KB
Volume
25
Category
Article
ISSN
0095-9782

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✍ Giuseppina Castronuovo; Vittorio Elia; Dimitrios Fessas; Filomena Velleca; Giuse 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 591 KB

The interaction in water of cyclomaltohexaose (a-cyclodextrin) with monocarboxylic acids from C 3 to C12 has been studied calorimetrically at 25 °C in phosphate buffer, pH 11.3. When a complex forms, calorimetry enables the calculation of both the enthalpy and the association constant, from which th