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Volumetric properties of (alkoxypropanol + n-alkanol) systems at 298.15 K

✍ Scribed by Amalendu Pal; Rekha Gaba


Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
254 KB
Volume
135
Category
Article
ISSN
0167-7322

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✦ Synopsis


Excess molar volumes V m E for binary liquid mixtures of (n-alkanol + 1-methoxy-2-propanol, 1-ethoxy-2-propanol, 1-propoxy-2-propanol, 1butoxy-2-propanol, or 1-tert-butoxy-2-propanol) have been measured as a function of composition using a continuous dilution dilatometer at 298.15 K and atmospheric pressure over the full range of composition. The n-alkanols were methanol, ethanol, and 1-propanol. The V m E for each of the mixture studied are negative over the whole mole fraction range. For each case, the V m E increases in a positive direction with increase in chain length of the n-alkanol. The V m E results have been used to estimate the excess partial molar volumes V Β―m,i E of the components.


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