Voltammetric studies and determination of xenon compounds in aqueous solutions
β Scribed by Francis X. Dias; Bruno Jaselskis
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 353 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0013-4686
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β¦ Synopsis
Xenon compounds in aqueous solution at the glassy carbon electrode are irreversibly reduced to xenon(O). The observed reduction potentials us see for xenon compounds are: (I) Perxenate -0.49 to -0.67 V with increasing pH from lO_ 14; (2) Xenon trioxide -0.54 to -0.48 V with increasing pH from 7-13. and (3) Xenon tiuoride at + 0.19 Vat pH 1.6. Platinum and mercury electrodes, are readily oxidized and are not suitable.
π SIMILAR VOLUMES
The solubility of carbon dioxide, krypton, and xenon has been measured at 1 Atm. total pressure and at temperatures of 25, 30, 37, and 45" in distilled water, 0.9 per cent sodium chloride, and .066 M phosphate buffer solution at pH 7.0. T h e solubility of the gases studied in aqueous solution decr
## AbStlXCt A method for the determmatlon of volatde compounds present m aqueous solutions IS presented, based on mlcroextractlon by demwng with 2-propanol The extraction properties of various solvents were exanuned and the method was optmuzed The method IS rapid and precse and enables detectlon h