## ANALYTICA ClitIMICA ACTA =7 'I'hc aluminum cloctrode is a Irighly polarizahlc clcctrode botll nnodically and cnthodically, the passivity of the metal being attributed to a film of aluminum osiclc! covering the clcctrode surface. 'I'hc clcctrodc potentials measured by clcctrochcn~ical techniques
Voltammetric, potentiometric and amperometric studies with a rotated aluminum wire electrode : A comparison of the baker and morrison cell with the raie.
β Scribed by I.M. Kolthoff; C.J. Sambucetti
- Publisher
- Elsevier Science
- Year
- 1960
- Tongue
- English
- Weight
- 689 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0003-2670
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π SIMILAR VOLUMES
In the first paper of this series 1 it WLS shown that the rotated aluminum clcctrotlc (KA1.E.) dots not function as a pa c!lcctrodc in acid medium but behaves as a ~OII electrode at a plr greater than about 9. Even tracts of fluoriclc ion depolarize the electrode in acid solutions and tllc elcctrod
A platinum rotating disk electrode (RDE) was used for the detailed voltammetric study of complexes: Fe(2,2'-dipyridyl)3(C10~)2, Fe(1,10-phenanthroline)3-(C104)2, Fe(cyclopentadienyl)2(ferrocene), and Co(2,2'-dipyridyl)3(C104)3 in acetonitrile (AN) solutions of 0.1 M NaC10 4. All the complexes react