Voltage programming in capillary electrochromatography
β Scribed by Baomin Xin; Milton L. Lee
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 87 KB
- Volume
- 11
- Category
- Article
- ISSN
- 1040-7685
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β¦ Synopsis
Voltage programming was explored to accelerate the elution of late-Ε½ . eluting components in capillary electrochromatography CEC separations. Voltage programming was demonstrated to be an effective alternative to composition gradient programming with the separation of a mixture of polycyclic aromatic hydrocarbons. While enabling short analysis times, voltage programming does not impose any special requirements on voltage isolation, sample introduction, and other concerns inherent in gradient systems.
π SIMILAR VOLUMES
The operational parameters and factors which control the performance Ε½ . of capillary electrochromatography CEC using commercially available CEC instrumentation are evaluated and discussed. The CEC of neutral or ion-suppressed acidic analytes shows marked advantages such as increased column efficien
## Enhancement of electroosmotic flow in capillary electrochromatography A major impediment to enhancing the speed of separation in capillary electrochromatography (CEC) is the upper limit on the electroosmotic flow (EOF) velocity by the maximal zeta potential of the chromatographic surface. Here,