Visible spectra of dicarbonyl substituted tris-bipyridyl ruthenium(II) complexes

✍ Scribed by William E. Ford; Melvin Calvin

• Book ID: 103017533
• Publisher: Elsevier Science
• Year: 1980
• Tongue: English
• Weight: 315 KB
• Volume: 76
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(80)80614-2

✦ Synopsis

The solLent dependence of the metal-to-hgand charge-transfer band pattern of tns-blpyrldyl ruthemum(I1) derwxtwes \rqth carbonyl substltuents 1s attnbuted to a reduction m the energy requued for electron transfer to the dxarbonylated blp> ndyl hgand wth an mcrease m solvent poktnty The mrxed-hgand dialkyl carboxyhc acid ester denvatwes of the tns(2.2'-blpyridyl)rutheruum(II) complex (abbrewated to [Ru(blpy)3 I"+), whch were first