Visible-Light Photoredox Catalysis: Aza-
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Condie, Allison G.; González-Gómez, José C.; Stephenson, Corey R. J.
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Article
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2010
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American Chemical Society
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English
⚖ 232 KB
We report the application of visible-light photoredox catalysis for the formation of C-C bonds between tertiary N-arylamines and nitroalkanes via an oxidative aza-Henry reaction. In the presence of 1 mol % Ir(ppy)(2)(dtbbpy)PF(6), efficient coupling of nitroalkanes with in situ-generated iminium ion