Viscosity of mixtures of fluoroalcohols and water at high pressures
β Scribed by S. Matsuo; R. Yamamoto; Y. Tanaka; H. Kubota
- Publisher
- Springer
- Year
- 1993
- Tongue
- English
- Weight
- 606 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0195-928X
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β¦ Synopsis
Viscosities of aqueous solutions of 2,2,2,-trifluoroethanol, 2,2,3,3-tctrafluoropropanol and 2,2,3,3,3-pentafluoropropanol have been measured with a falling-body viscometer. Measurements were performed at temperatures from 298 to 323 K and at pressures up to 80 MPa with an estimated uncertainty of _+2%. Viscosities obtained for these mixtures are represented by a simple empirical equation within the experimental uncertainty. The composition dependence of the viscosity is compared with that for mixtures of hydrocarbon alcohols and water.
π SIMILAR VOLUMES
The relationship between p \* t and TR for nonpolar gases a t normal pressures is used to predict the viscosity for their mixtures. For such mixtures, pseudocritical temperatures are used t o obtain TR. T o establish tm for a mixture, a binary interaction model has been applied that utilizes composi