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Viscosity and temperature effects in excited state double proton transfer: Luminescence of 1-azacarbazole dimers in solid state and solution

✍ Scribed by J. Waluk; B. Pakuła


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
209 KB
Volume
114
Category
Article
ISSN
0022-2860

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✍ Ferdinand Männle; Iwona Wawer; Hans-Heinrich Limbach 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 378 KB

Using dynamic 15N CPMAS NMR spectroscopy a novel double proton transfer was detected in the cyclic hydrogen bonded dimers of polycrystalline tSN,ZSN'-di-(4-bromophenyl)-formamidine. Rate constants of this process, which is degenerate within the margin of error, were obtained by lineshape (kl2 = 10 6