Viscosities and excess viscosities of aqueous solutions of some diethanolamines
β Scribed by Faisal Islam Chowdhury; Shamim Akhtar; Muhammad A. Saleh
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 812 KB
- Volume
- 155
- Category
- Article
- ISSN
- 0167-7322
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β¦ Synopsis
Viscosities, Ξ·, of aqueous diethanolamine (DEA), methyldiethanolamine (MDEA), ethyldiethanolamine (EDEA) and n-butyldiethanolamine (BDEA) solutions were determined at an interval of 5 K between 303.15 and 323.15 K at different compositions in the range 0 β€ x 2 β€ 1, where x 2 is the mole fraction of alkanolamines. Excess viscosities, Ξ· E , have been found to be positive for all systems in the whole range of composition at all temperatures. The heights of maxima in Ξ· E vary as W + DEA N N W + MDEA N W + EDEA N W + BDEA. The effect of temperature on both Ξ· and Ξ· E is significantly largethe more the temperature the less the viscosity as well as the excess viscosity. For all the systems, Ξ· and Ξ· E data have been fitted well with six degree polynomial and Redlich-Kister equations, respectively.
π SIMILAR VOLUMES
## THE equation proposed by Jones and Dole1 serves to represent the experimental results for the viscosity, 7, of solutions of electrolytes. The range of validity of the equation depends on the solute, solvent and temperature, for aqueous solutions of uni-univalent salts the equation is usually ob