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Viscoelastic spectra of soft polymer interfaces obtained by noise analysis of AFM cantilevers

✍ Scribed by Gelbert, Martin; Roters, Andreas; Schimmel, Martin; Rühe, Jürgen; Johannsmann, Diethelm


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
156 KB
Volume
27
Category
Article
ISSN
0142-2421

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✦ Synopsis


The dynamic properties of the environment of an atomic force microscopy (AFM) tip can be probed by observing the cantileverÏs mechanical noise. In the absence of viscoelastic dispersion, the power spectral density is well approximated by the resonance of a simple harmonic oscillator. By Ðtting resonance curves to the data, the friction coefficient n, the e †ective mass m and the e †ective spring constant j are obtained. The variation of these parameters with the cantilever-substrate distance reÑects the hydrodynamic and viscoelastic interactions between the cantilever and the surface. For cantilevers approaching soft polymer brushes, one Ðnds an elastic interaction extending to about the brush height. The viscous interaction, on the other hand, is more long-ranged. For tips deeply immersed into the brush the noise spectra are no longer described by a simple harmonic oscillator. There is an excess noise at low frequencies that we attribute to viscoelastic dispersion. Hydrodynamic interactions, which should also induce deviations from the pure resonance behaviour should be largely screened by the polymer chains. By use of the Ñuctuation dissipation theorem, the viscoelastic spectrum n [ x ] can be derived explicitly from the noise power spectrum.


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