## Abstract Two vinyl chloride polymers with intrinsic viscosities of 0.65 and 1.17 were compounded with four plasticizers. Stress relaxation data were obtained at three temperatures and analyzed by a step function of seven parameters in Maxwell representation. The relaxation times were nearly inde
✦ LIBER ✦
Viscoelastic behavior of plasticized polyvinyl chloride at large deformations. II. Creep
✍ Scribed by Sabia, Raffaele ;Eirich, F. R.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1963
- Tongue
- English
- Weight
- 623 KB
- Volume
- 1
- Category
- Article
- ISSN
- 0449-2951
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✦ Synopsis
Abstract
Plasticized polyvinyl chloride has been found to undergo a permanent deformation when strained past 100%. At the same strains, internal energy effects become pronounced as reflected in the stress‐strain curves. Plasticizer efficiency has been evaluated in several respects, namely rubber‐like behavior, recovery, glass transition, set, and stress‐strain at break. While no single plasticizer stands out, the following sequence has been established with respect to the first four aspects listed above: DOA ≥ TCP > DPP ≥ ARO.
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