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Viscoelastic behavior of plasticized polyvinyl chloride at large deformations. II. Creep

✍ Scribed by Sabia, Raffaele ;Eirich, F. R.


Publisher
Wiley (John Wiley & Sons)
Year
1963
Tongue
English
Weight
623 KB
Volume
1
Category
Article
ISSN
0449-2951

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✦ Synopsis


Abstract

Plasticized polyvinyl chloride has been found to undergo a permanent deformation when strained past 100%. At the same strains, internal energy effects become pronounced as reflected in the stress‐strain curves. Plasticizer efficiency has been evaluated in several respects, namely rubber‐like behavior, recovery, glass transition, set, and stress‐strain at break. While no single plasticizer stands out, the following sequence has been established with respect to the first four aspects listed above: DOA ≥ TCP > DPP ≥ ARO.


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Viscoelastic behavior of plasticized pol
✍ Sabia, Raffaele ;Eirich, F. R. 📂 Article 📅 1963 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 586 KB

## Abstract Two vinyl chloride polymers with intrinsic viscosities of 0.65 and 1.17 were compounded with four plasticizers. Stress relaxation data were obtained at three temperatures and analyzed by a step function of seven parameters in Maxwell representation. The relaxation times were nearly inde