Violation of the electroneutrality condition in confined unsymmetrical electrolytes

✍ Scribed by Marcelo Lozada-Cassou; Wilmer Olivares; Belky Sulbarán; Yu Jiang

• Book ID: 103896204
• Publisher: Elsevier Science
• Year: 1996
• Tongue: English
• Weight: 521 KB
• Volume: 231
• Category: Article
• ISSN: 0378-4371
• DOI: 10.1016/0378-4371(95)00451-3

✦ Synopsis

The three-point extension hypemetted chain-mean spherical theory of liquids is solved for a system formed by two charged plates immersed in a model unsymmetrical electrolyte. The charge on the plates is fixed as a function of the distance between the plates. The extent to which the local electroneutrality condition is not satisfied is studied. The plate-plate force is calculated and compared to that for confined symmetrical electrolytes.