Vinylidene, Vinyl, and Carbene Ruthenium Complexes with Chelating Diphosphanes as Ligands
✍ Scribed by Helmut Werner; Stefan Jung; Pablo González-Herrero; Kerstin Ilg; Justin Wolf
- Publisher
- John Wiley and Sons
- Year
- 2001
- Tongue
- English
- Weight
- 309 KB
- Volume
- 2001
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
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## Abstract Di‐ and trinuclear complexes of copper(I) bearing bis‐ or tris‐N‐heterocyclic carbene ligands have been prepared and evaluated as catalysts in nitrene transfer reactions from PhI=NTs to unsaturated and saturated substrates (olefin aziridination and C–H bond amidation) and carbene transf
## Abstract The mononuclear cationic Rh^I^ complexes [Rh(cod)(mdd)]^+^X^−^ and [Rh(CO)~2~(mdd)]^+^X^−^ (X = BPh~4~, PF~6~) containing the chelating bidentate __N__‐heterocyclic carbene ligand 1,1′‐methylene‐3,3′‐dimethyldiimidazoline‐2,2′‐diylidene (mdd) have been synthesised and spectroscopically