Vinylidene: probable intemediacy in methylenecyclopropane decomposition and heat of formation

Evidence for strongly temperature-depend

Evidence for strongly temperature-dependent A factors in alkane decomposition and high heats of formation for alkyl radicals

✍ Wing Tsang 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 English ⚖ 835 KB

## Abstract The experimental data on alkane decomposition from shock‐tube and radical buffer studies and radical combination from very‐low‐pressure pyrolysis and modulation spectroscopy are shown to be consistent. They lead to experimental __A__ factors which decrease by factors of 10–2000 from 300