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Vinylic Substitutions Promoted by PhSeZnCl: Synthetic and Theoretical Investigations

✍ Scribed by Stefano Santoro; Benedetta Battistelli; Lorenzo Testaferri; Marcello Tiecco; Claudio Santi


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
412 KB
Volume
2009
Category
Article
ISSN
1434-193X

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Synthetic and Theoretical Investigations
✍ Mamta Dadwal; Manoj K. Kesharwani; Vaishalee Danayak; Bishwajit Ganguly; Shaikh 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 439 KB

## Abstract The conjugate addition of nucleophiles such as allylmercaptan, allyl‐ and homoallylmalonate and diallylamine to β‐furyl enones and acrylate, provides the Michael adducts in good yield. A facile intramolecular Diels–Alder reaction between the unsaturated tether and the furan diene ensues