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Vinylcyclopentene synthesis via phenylthio radical catalyzed addition of electron deficient alkynes to substituted vinylcyclopropanes

✍ Scribed by Ken S Feldman; Robert E Ruckle Jr.; Anthony L Romanelli

Book ID: 104244601
Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 283 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)93486-0

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✦ Synopsis

Treatment of either t-butyl ester-or benzylether-substituted vinylcyclopropanes with an excess of ester-or sulfone-bearing alkynes in the presence of phenylthio radical in benzene afforded moderate yields of functional&d vinylcyclopentene products as mixtures of stereoisomers.

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